1.Xu, Q. ‡; Nie, Y. ‡; Haaksma, J.-J.; Zhang, R.; Douglas, N.; Mei, F.; Scola, P. M.; Williams, C.; Johnson, A. J.; Wendlandt, A. E. Alcohol group migration by proximity-enhanced H atom abstraction. Nature, 2026, 652, 660-666.
2.Xu, Q.; Hoye, T. R. Free carbenes from complementarily paired alkynes. Nat. Chem. 2024, 16,1083-1092. Highlighted by Nat. Chem.
3.Xu, Q.; Shi, J.; Hoye, T. R. Pyrrole-stabilized free carbenes (from alkynyl imidates/aldimines and electrophilic alkynes) enroute to pyrrolone- and pyrrole-containing products. Nat. Synth. 2026, 5, 95-102.
4.Xu, Q.; Hoye, T. R. A cascade of strain-driven events converting benzynes to alkynylbenzocyclobutenes to 1,3-dien-5-ynes to cyclic allenes to benzocyclohexadienones. J. Am. Chem. Soc. 2024, 146, 6438-6443.
5.Xu, Q.; Hoye, T. R. A distinct mode of strain-driven cyclic allene reactivity: Group migration to the central allene carbon atom. J. Am. Chem. Soc. 2023, 145, 9867-9875.
6.Xu, Q.; Hoye, T. R. Electronic character of α,3-dehydrotoluene intermediates generated from isolable allenyne-containing substrates. Angew. Chem. Int. Ed. 2022, 61, e202207510.
7.Wang, R.‡; Xu, Q.‡; Hoye, T. R. Reactions of electrophilic allenoates [and isocyanates/isothio-cyanate] with a 2-alkynylpyridine via a free carbene intermediate. Org. Lett. 2024, 26, 7805−7808.
8.Tang, R.; Xu, Q.; Hoye, T. R. A case of competitive aromatization vs. sigmatropic [1,5]-hydrogen atom migration in a 1,2,4-cyclohexatriene intermediate derived from a bis-enyne cyclization. Molecules 2025, 30, 2610.
9.Wang, H.; Xu, Q.; Yu, S. Visible light-induced aryltrifluoromethylation of hydroxy alkenes via radical trifluoromethylation-triggered aryl and heteroaryl migration. Org. Chem. Front. 2018, 5, 2224-2228.
10.Wang, H.; Xu, Q.; Shen, S.; Yu, S. Synthesis of quinolines through three-component cascade annulation of aryl diazonium salts, nitriles, and alkynes. J. Org. Chem. 2017, 82, 770-775.