朱从青
职务:
联系电话:
办公地址: 化学楼D506
电子邮箱: zcq@nju.edu.cn
课题组主页:
个人简介

朱从青,教授,博导。2008年于安庆师范大学获学士学位;2014年于厦门大学获博士学位(导师:夏海平院士);随后分别在厦门大学和麻省理工学院从事博士后研究(导师:Richard Schrock教授);2016年入职南京大学、配位化学全国重点实验室,开展独立研究工作


长期从事金属有机化学、配位化学基础研究。在Nat. Chem.Nat. Synth.PNASChemCCS ChemJ. Am. Chem. Soc.Angew. Chem. Int. Ed.Nat. CommunAcc. Chem. Res.Chem. Soc. Rev.等期刊发表论文80余篇。担任Organometallics, Chin. J. Chem.等期刊编委。


曾获得/入选基金委青A(原杰青)项目、国家青年拔尖人才、国家自然科学二等奖(排名4/5)、首届黄耀曾金属有机化学青年奖、中国化学会菁青化学新锐奖、中国科协青年人才托举工程、江苏省攀登项目、江苏省杰青项目、江苏省“333工程”第二层次人才、江苏省双创人才、江苏特聘教授等。


欢迎对我们研究感兴趣的硕/博研究生、博士后加入。



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工作经历

2016.11-至   今   南京大学化学化工学院教授

2015.10-2016.10   麻省理工学院化学系          Postdoctoral Associate (Richard R. Schrock教授)

2014.06-2015.10   能源材料化学协同创新中心    iChEM Fellow(夏海平 院士)

2008.09-2014.06   厦门大学化学化工学院博士研究生(夏海平 院士)

2004.09-2008.06   安庆师范大学化学化工学院本科生




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研究方向

1. 锕系金属有机/配位化学;

2. 金属-金属键化学

3. 小分子活化

学术成果

长期从事金属有机化学、配位化学基础研究。取得系列创新成果:1)创制独特双层N-P配体,首次实现同一分子内多根An-TM键的构筑,突破此前仅存在单根An-TM键的局限;2)提出增强轨道重叠和过渡金属电子富集双重策略,构筑首例An-TM累积双键、三键,开启锕系金属多重键研究新篇章;3)发现两原子间共存双中心单电子σ键和单电子π键的成键新模式,突破成键理论边界。在Nat. Chem.Nat. Synth.PNASChemCCS ChemJ. Am. Chem. Soc.Angew. Chem. Int. Ed.Nat. CommunAcc. Chem. Res.Chem. Soc. Rev.等期刊发表论文80余篇,代表性论文如下:


33. W. Sheng, F. Xie, T. Rajeshkumar, Y. Zhao, Y. Jiang, W. Chen, S. Ye*, L. Maron*, C. Zhu*, A crystalline dithorium complex with a Th-Th bond. Nat. Synth. 20254, 987-994.

32. W. Sheng, T. Rajeshkumar, Q. Zhao, J. Xie, L. Maron,C. Zhu*, Synthesis and catalytic activity of thorium nitride complex from dinitrogen reduction.J. Am. Chem. Soc. 2025147, 7203-7208.

31. Y. Li, C. Ding, Q. Zhao, S. Wang, J. Xie, S. Pan*,C. Zhu*, Synthesis and structure of uranium disilyl-substituted alkylidene complexesJ. Am. Chem. Soc. 2025147, 8991-8999.

30. P. Chen, Y. Li, J. Ma, J. Zhu, J. Xie, M. SolàC. Zhu*, Q. Zhu*, Neutral all-metal σ-aromaticity in a rhombic clusterJ. Am. Chem. Soc. 2025147, 14769-14776.

29. X. Gong, L.-W. Ye, Z.-C. Han, Y. Zhao, J. Xie, H.-S. Hu, J. Li*,C. Zhu*,Unprecedented Tetravalent Uranium Photocatalysts for Efficient C(sp3)–C(sp3) Bond Cleavage and FormationAngew. Chem. Int. Ed.202564, e202502634.

28. J. Shen, Z. Zhang, X. Ke, L. Peng, Q. Zhao, C. Zhu*, Q. Zhu*, Isolable zero-valent ditin(0) and diplumbum(0) complexes. Nat. Commun. 202516, 2588.

27. W. Fang, Y. Li, T. Zhang, T. Rajeshkumar, I. Rosal, Y. Zhao, T. Wang, S. Wang, L. Maron, C. Zhu*, Oxidative addition of E-H (E = C, N) bonds to transient uranium(II) centers. Angew. Chem. Int. Ed. 202463, e202407339.

26. K. Li, I. Rosal, Y. Zhao, L. Maron*, C. Zhu*, Planar tetranuclear uranium hydride cluster supported by ansa-bis(cyclopentadienyl) ligands. Angew. Chem. Int. Ed. 202463, e202405494.

25. W. Sheng, T. Rajeshkumar, Y. Zhao, L. Maron, C. Zhu*, Electronic delocalization and σ-aromaticity in heterometallic cluster with multiple thorium-palladium bondsJ. Am. Chem. Soc. 2024146, 12790-12798.

24. X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex. Natl. Sci. Rev. 202310, nwac144.

23. J. Shen, T. Rajeshkumar, G. Feng, Y. Zhao, S. Wang, L. Maron*, C. Zhu*,Complexes featuring a cis-[MUM] core (M = Rh, Ir): A new route to uranium-metal multiple bonds. Angew. Chem. Int. Ed. 202362, e202303379 

22. Q. Zhu†, W. Fang, L. Maron, C. Zhu*, Heterometallic clusters with uranium–metal bonds supported by double-layer nitrogen–phosphorus ligands. Acc. Chem. Res.202255, 1718-1730.

21. W. Fang, Q. Zhu*, C. Zhu*, Recent advances in heterometallic clusters with f-block metal-metal bonds: synthesis, reactivity and applications. Chem. Soc. Rev. 202251, 8434-8449.

20. P. Wang, I. Douair, Y. Zhao, R. Ge, J. Wang, S. Wang, L. Maron*C. Zhu*, Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium–metal triple bonds. Chem.20228, 1361–1375.

19. X. Xin, I. Douair, T. Rajeshkumar, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Photochemical synthesis of transition metal-stabilized uranium(VI) nitride complexes. Nat. Commun. 202213, 3809.

18. W. Fang, I. Douair, A. Hauser, K. Li, Y. Zhao, P. W. Roesky, S. Wang, L. Maron*, C. Zhu*, Uranium(III)-phosphorus(III) synergistic activation of white phosphorus and arsenic. CCS Chem. 20224, 2630–2638.

17. W. Fang, S. Pan, W. Su, S. Wang, L. Zhao*, G. Frenking*,C. Zhu*, Complex featuring two double dative bonds between carbon(0) and uranium. CCS Chem.20224, 1921-1929.

16. K. Shi, I. Douair, G. Feng, P. Wang, Y. Zhao, L. Maron*C. Zhu*, Heterometallic clusters with multiple rare earth metal−transition metal bonding. J. Am. Chem. Soc. 2021,143, 5998–6005.


15. X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron,C. Zhu,* Dinitrogen cleavage by a heterometallic cluster featuring multiple uranium–rhodium bonds. J. Am. Chem. Soc. 2020142, 15004-15011. 

14. P. Wang, I. Douair, Y. Zhao, S. Wang, J. Zhu, L. Maron,* C. Zhu,*  Facile dinitrogen and dioxygen cleavage by a uranium(III) complex: Cooperativity between the non-innocent ligand and the uranium center. Angew. Chem. Int. Ed. 2021, 60, 473-479. 

13. G. Feng, M. Zhang, D. Shao, X. Wang, S. Wang, L. Maron,* C. Zhu,* Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds. Nature Chem. 201911, 248-253. (Highlighted by C&E News)

12. G. Feng, M. Zhang, P. Wang, S. Wang, L. Maron,* C. Zhu,* Identification of a uranium–rhodium triple bond in a heterometallic clusterPNAS 2019116, 17654-17658. 

11. W. Su, S. Pan, X. Sun, S. Wang, L. Zhao,* G. Frenking,* C. Zhu,* Double dative bond between divalent carbon(0) and uranium. Nature Commun.20189, 4997. 

10. C. Zhu, H. Xia,* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metal. Acc. Chem. Res.201851, 1691–1700.

9. C. Zhu, J. Zhu, X. Zhou, Q. Zhu, Y. Yang, T. Wen, H. Xia,* Isolation of an Eleven-Atom Polydentate Carbon-Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne.Angew. Chem. Int. Ed., 2018, 57, 3154-3157.

8. C. Zhu, J. Wu, S. Li, Y. Yang, J. Zhu, X. Lu, H. Xia,* Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings. Angew.Chem. Int. Ed.2017, 56, 9067-9071.

7. C. Zhu,+ C. Yang,+ Y. Wang, G. Lin, Y. Yang, X. Wang, J. Zhu, X. Chen, X. Lu,* G. Liu,* H. Xia,* CCCCC Pentadentate Chelates with Planar Möbius Aromaticity and Unique Properties.Sci. Adv.2016, 2, e1601031.

6. C. Zhu, Y. Yang, J. Wu, M. Luo, J. Fan, J. Zhu,* H. Xia,* Five-membered cyclic metal carbyne: Synthesis of osmapentalynes by the reactions of osmapentalene with allene, alkyne, and alkene.Angew. Chem.Int. Ed.2015, 54, 7189-7192.

5. C. Zhu, Y. Yang, M. Luo, C. Yang, J. Wu, L. Chen, G. Liu, T. Wen, J. Zhu,* H. Xia,* Stabilizing two classical anti-aromatic frameworks: Demonstration of photoacoustic imaging and photothermal effect in metalla-aromatics.Angew. Chem. Int. Ed., 2015, 54, 6181-6185

4. C. Zhu, X. Zhou, H. Xing, K. An, J. Zhu,* H. Xia,* σ-Aromaticity in an unsaturated ring: Osmapentalene derivatives containing a metallacyclopropene unit.Angew. Chem. Int. Ed., 2015, 54, 3102-3106.

3. C. Zhu, M. Luo, Q. Zhu, J. Zhu,* P. v. R. Schleyer, J. I.-C. Wu, X. Lu, H. Xia,* Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums.Nature Commun.20145, 3265-3271.

2. C. Zhu, Q. Zhu, J. Fan, J. Zhu, X. He, X.-Y. Cao,* H. Xia,* A metal-bridged tricyclic aromatic system: synthesis of osmium polycyclic aromatic complexes.Angew. Chem. Int. Ed.2014, 53, 6232-6236.

1. C. Zhu, S. Li, M. Luo, X. Zhou, Y. Niu, M. Lin, J. Zhu,* Z. Cao, X. Lu, T. Wen, Z. Xie, P. v. R. Schleyer, H. Xia,* Stabilization of anti-aromatic and strained five-membered rings with a transition metal. Nature Chem.20135, 698-703.

课程名称、上课时间地点

1.导向有机合成的金属有机化学

2.有机化学

教学大纲、考试要求
教学资源(上课讲义、参考资料等)
课题组风采