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个人简介
朱从青,教授,博导。2008年于安庆师范大学获学士学位;2014年于厦门大学获博士学位(导师:夏海平院士);随后分别在厦门大学和麻省理工学院从事博士后研究(导师:Richard Schrock教授);2016年入职南京大学、配位化学全国重点实验室,开展独立研究工作。 长期从事金属有机化学、配位化学基础研究。在Nat. Chem.、Nat. Synth.、PNAS、Chem、CCS Chem、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commun、Acc. Chem. Res.、Chem. Soc. Rev.等期刊发表论文80余篇。担任Organometallics, Chin. J. Chem.等期刊编委。 曾获得/入选基金委青A(原杰青)项目、国家青年拔尖人才、国家自然科学二等奖(排名4/5)、首届黄耀曾金属有机化学青年奖、中国化学会菁青化学新锐奖、中国科协青年人才托举工程、江苏省攀登项目、江苏省杰青项目、江苏省“333工程”第二层次人才、江苏省双创人才、江苏特聘教授等。 欢迎对我们研究感兴趣的硕/博研究生、博士后加入。 展示全部
工作经历
2016.11-至 今 南京大学化学化工学院教授 2015.10-2016.10 麻省理工学院化学系 Postdoctoral Associate (Richard R. Schrock教授) 2014.06-2015.10 能源材料化学协同创新中心 iChEM Fellow(夏海平 院士) 2008.09-2014.06 厦门大学化学化工学院博士研究生(夏海平 院士) 2004.09-2008.06 安庆师范大学化学化工学院本科生 展示全部
研究方向
1. 锕系金属有机/配位化学; 2. 金属-金属键化学 3. 小分子活化 学术成果
长期从事金属有机化学、配位化学基础研究。取得系列创新成果:1)创制独特双层N-P配体,首次实现同一分子内多根An-TM键的构筑,突破此前仅存在单根An-TM键的局限;2)提出增强轨道重叠和过渡金属电子富集双重策略,构筑首例An-TM累积双键、三键,开启锕系金属多重键研究新篇章;3)发现两原子间共存双中心单电子σ键和单电子π键的成键新模式,突破成键理论边界。在Nat. Chem.、Nat. Synth.、PNAS、Chem、CCS Chem、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commun、Acc. Chem. Res.、Chem. Soc. Rev.等期刊发表论文80余篇,代表性论文如下: 33. W. Sheng†, F. Xie†, T. Rajeshkumar, Y. Zhao, Y. Jiang, W. Chen, S. Ye*, L. Maron*, C. Zhu*, A crystalline dithorium complex with a Th-Th bond. Nat. Synth. 2025, 4, 987-994. 32. W. Sheng, T. Rajeshkumar, Q. Zhao, J. Xie, L. Maron,C. Zhu*, Synthesis and catalytic activity of thorium nitride complex from dinitrogen reduction.J. Am. Chem. Soc. 2025, 147, 7203-7208. 31. Y. Li†, C. Ding†, Q. Zhao, S. Wang, J. Xie, S. Pan*,C. Zhu*, Synthesis and structure of uranium disilyl-substituted alkylidene complexes. J. Am. Chem. Soc. 2025, 147, 8991-8999. 30. P. Chen, Y. Li, J. Ma, J. Zhu, J. Xie, M. Solà, C. Zhu*, Q. Zhu*, Neutral all-metal σ-aromaticity in a rhombic cluster. J. Am. Chem. Soc. 2025, 147, 14769-14776. 29. X. Gong†, L.-W. Ye†, Z.-C. Han†, Y. Zhao, J. Xie, H.-S. Hu, J. Li*,C. Zhu*,Unprecedented Tetravalent Uranium Photocatalysts for Efficient C(sp3)–C(sp3) Bond Cleavage and Formation. Angew. Chem. Int. Ed.2025, 64, e202502634. 28. J. Shen, Z. Zhang, X. Ke, L. Peng, Q. Zhao, C. Zhu*, Q. Zhu*, Isolable zero-valent ditin(0) and diplumbum(0) complexes. Nat. Commun. 2025, 16, 2588. 27. W. Fang†, Y. Li†, T. Zhang†, T. Rajeshkumar, I. Rosal, Y. Zhao, T. Wang, S. Wang, L. Maron, C. Zhu*, Oxidative addition of E-H (E = C, N) bonds to transient uranium(II) centers. Angew. Chem. Int. Ed. 2024, 63, e202407339. 26. K. Li, I. Rosal, Y. Zhao, L. Maron*, C. Zhu*, Planar tetranuclear uranium hydride cluster supported by ansa-bis(cyclopentadienyl) ligands. Angew. Chem. Int. Ed. 2024, 63, e202405494. 25. W. Sheng, T. Rajeshkumar, Y. Zhao, L. Maron, C. Zhu*, Electronic delocalization and σ-aromaticity in heterometallic cluster with multiple thorium-palladium bonds. J. Am. Chem. Soc. 2024, 146, 12790-12798. 24. X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex. Natl. Sci. Rev. 2023, 10, nwac144. 23. J. Shen, T. Rajeshkumar, G. Feng, Y. Zhao, S. Wang, L. Maron*, C. Zhu*,Complexes featuring a cis-[M⇉U⇇M] core (M = Rh, Ir): A new route to uranium-metal multiple bonds. Angew. Chem. Int. Ed. 2023, 62, e202303379 21. W. Fang, Q. Zhu*, C. Zhu*, Recent advances in heterometallic clusters with f-block metal-metal bonds: synthesis, reactivity and applications. Chem. Soc. Rev. 2022, 51, 8434-8449. 20. P. Wang, I. Douair, Y. Zhao, R. Ge, J. Wang, S. Wang, L. Maron*, C. Zhu*, Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium–metal triple bonds. Chem.2022, 8, 1361–1375. 18. W. Fang, I. Douair, A. Hauser, K. Li, Y. Zhao, P. W. Roesky, S. Wang, L. Maron*, C. Zhu*, Uranium(III)-phosphorus(III) synergistic activation of white phosphorus and arsenic. CCS Chem. 2022, 4, 2630–2638. 16. K. Shi, I. Douair, G. Feng, P. Wang, Y. Zhao, L. Maron*, C. Zhu*, Heterometallic clusters with multiple rare earth metal−transition metal bonding. J. Am. Chem. Soc. 2021,143, 5998–6005. 15. X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron,* C. Zhu,* Dinitrogen cleavage by a heterometallic cluster featuring multiple uranium–rhodium bonds. J. Am. Chem. Soc. 2020, 142, 15004-15011. 14. P. Wang, I. Douair, Y. Zhao, S. Wang, J. Zhu, L. Maron,* C. Zhu,* Facile dinitrogen and dioxygen cleavage by a uranium(III) complex: Cooperativity between the non-innocent ligand and the uranium center. Angew. Chem. Int. Ed. 2021, 60, 473-479. 13. G. Feng, M. Zhang, D. Shao, X. Wang, S. Wang, L. Maron,* C. Zhu,* Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds. Nature Chem. 2019, 11, 248-253. (Highlighted by C&E News) 12. G. Feng, M. Zhang, P. Wang, S. Wang, L. Maron,* C. Zhu,* Identification of a uranium–rhodium triple bond in a heterometallic cluster. PNAS 2019, 116, 17654-17658. 11. W. Su, S. Pan, X. Sun, S. Wang, L. Zhao,* G. Frenking,* C. Zhu,* Double dative bond between divalent carbon(0) and uranium. Nature Commun., 2018, 9, 4997. 10. C. Zhu, H. Xia,* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metal. Acc. Chem. Res., 2018, 51, 1691–1700. 9. C. Zhu, J. Zhu, X. Zhou, Q. Zhu, Y. Yang, T. Wen, H. Xia,* Isolation of an Eleven-Atom Polydentate Carbon-Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne.Angew. Chem. Int. Ed., 2018, 57, 3154-3157. 8. C. Zhu, J. Wu, S. Li, Y. Yang, J. Zhu, X. Lu, H. Xia,* Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings. Angew.Chem. Int. Ed., 2017, 56, 9067-9071. 7. C. Zhu,+ C. Yang,+ Y. Wang, G. Lin, Y. Yang, X. Wang, J. Zhu, X. Chen, X. Lu,* G. Liu,* H. Xia,* CCCCC Pentadentate Chelates with Planar Möbius Aromaticity and Unique Properties.Sci. Adv., 2016, 2, e1601031. 6. C. Zhu, Y. Yang, J. Wu, M. Luo, J. Fan, J. Zhu,* H. Xia,* Five-membered cyclic metal carbyne: Synthesis of osmapentalynes by the reactions of osmapentalene with allene, alkyne, and alkene.Angew. Chem.Int. Ed., 2015, 54, 7189-7192. 5. C. Zhu, Y. Yang, M. Luo, C. Yang, J. Wu, L. Chen, G. Liu, T. Wen, J. Zhu,* H. Xia,* Stabilizing two classical anti-aromatic frameworks: Demonstration of photoacoustic imaging and photothermal effect in metalla-aromatics.Angew. Chem. Int. Ed., 2015, 54, 6181-6185 4. C. Zhu, X. Zhou, H. Xing, K. An, J. Zhu,* H. Xia,* σ-Aromaticity in an unsaturated ring: Osmapentalene derivatives containing a metallacyclopropene unit.Angew. Chem. Int. Ed., 2015, 54, 3102-3106. 3. C. Zhu, M. Luo, Q. Zhu, J. Zhu,* P. v. R. Schleyer, J. I.-C. Wu, X. Lu, H. Xia,* Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums.Nature Commun., 2014, 5, 3265-3271. 2. C. Zhu, Q. Zhu, J. Fan, J. Zhu, X. He, X.-Y. Cao,* H. Xia,* A metal-bridged tricyclic aromatic system: synthesis of osmium polycyclic aromatic complexes.Angew. Chem. Int. Ed., 2014, 53, 6232-6236. 1. C. Zhu, S. Li, M. Luo, X. Zhou, Y. Niu, M. Lin, J. Zhu,* Z. Cao, X. Lu, T. Wen, Z. Xie, P. v. R. Schleyer, H. Xia,* Stabilization of anti-aromatic and strained five-membered rings with a transition metal. Nature Chem., 2013, 5, 698-703. 课程名称、上课时间地点
1.导向有机合成的金属有机化学 2.有机化学 教学大纲、考试要求
教学资源(上课讲义、参考资料等)
课题组风采
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