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个人简介
王毅,男,1983年生,南京大学化学化工学院教授,博士生导师。 2005年本科毕业于南京大学,2010年获得英国爱丁堡大学有机化学博士学位。2011-2013年在英国圣安德鲁斯大学从事博士后研究,2014年至2019年任南京大学副教授。研究方向为有机氟化学、金属有机化学。近年来致力于氟化试剂的开发及电化学应用。发表包括Angew.Chem.、Nat. Commun.、 Science Advances、ACS Catal.等40多篇较有影响力的科研论文,申请50多项国家专利,获2021 年度Thieme化学奖,2023年入选国家特殊人才支持计划青年项目。 课题组诚聘博士后,推荐申请博士后创新人才支持计划,基本年薪40万,南京大学和江苏省配套个人待遇;南京大学毓秀青年学者计划,年薪35-60万。详情请联系yiwang@nju.edu.cn。 课题组网站:https://fluorine.nju.edu.cn/ MO源中心网站:http://molab.nju.edu.cn/ 马鞍山研究院网站:https://www.njumas.com/ 展示全部
工作经历
2011-2012年于英国圣安德鲁斯大学从事博士后研究工作。 2013-2014年任南京大学国家863计划新材料MO源中心副研究员。 2014-2019年任化学化工学院副教授,博士生导师。 2020年至今任化学化工学院教授 展示全部
研究方向
有机氟化学、金属有机合成与催化、半导体材料、能源材料 研究方向主要针对氟化工大量惰性副产物难以活化利用的挑战,采用弱键牵引的策略,开展惰性氟源的改造通过特殊设计制备的肟氯酯、磺酰咪唑盐、羟胺甲酸乙酯、肼基甲酸酯等活化基团,将含氟工业品用于新型试剂和功能砌块的转化利用中,在减少氯氟烃等有害物质排放的同时,获得了成本低廉的高附加值氟化工产品。 光催化含氟官能化:利用光催化反应机制,实现三氟乙酸、三氟甲磺酸、硫酰氟气体、氟利昂-22、三氟乙醇等大宗工业品的温和转化,解决了现有氧化还原活性试剂不能适用于含氟官能团的固有缺陷,突破传统活化策略的能量局限和断键模式,使原先缺乏清晰认识的弱键选择性断裂机制得到充分阐释。 电化学含氟官能团修饰:本团队长期致力于绿色可控的电化学有机合成研究,利用电压和电流的精准调控实现对化学反应活性的特异选择。依托金属协同催化,结合双极成对电解的优势,开发了一系列高效构建含氟官能团邻位修饰策略,包括芳基化、硫化、氧化、胺化、硼化等电化学合成方法,利用本组发展的电化学诱发的自由基试剂,包括肼甲酸甲酯、磺酰咪唑盐、双三氟甲磺酰胺等,实现无过渡金属催化条件下的电化学脱胺偶联以及脱氧偶联等,为电化学合成提供新型策略。 学术成果
(1) Zhang, Weigang#; Zou, Zhenlei#; Wang, Yuanheng; Wang, Yi*; Liang, Yong*; Wu, Zhengguang*; Zheng, Youxuan; Pan, Yi; Leaving Group Assisted Strategy for Photoinduced Fluoroalkylations Using N-Hydroxybenzimidoyl Chloride Esters , Angew. Chem.Int. Ed, 2019, 58(2): 624-627. (2) Ni, Shengyang#; Li, Chun Xiao#; Mao, Yu; Han, Jianlin*; Wang, Yi*; Yan, Hong*; Pan, Yi; Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C-N bond activation , Science Advances, 2019, 5: eaaw9516. (3) Zhang, Qiang; Li, Xiaojuan; Zhang, Weigang; Ni, Shengyang; Wang, Yi*; Pan, Yi; Decarboxylative Borylation of Stabilized and Activated Carbon Radicals, Angew. Chem.Int. Ed, 2020, 59(49): 21875-21879. (4) Yongyuan, Gao; Zhengguang, Wu; Lei, Yu; Yi, Wang*; Yi, Pan; Alkyl Carbazates for Electrochemical Deoxygenative Functionalization of Heteroarenes, Angew. Chem.Int. Ed, 2020, 132(27): 10951-10955. (5) Zhang, Weigang; Zou, Zhenlei; Zhao, Wenxuan; Lu, Shuo; Wu, Zhengguang; Huang, Mengjun; Wang, Xiaochen; Wang, Yi*; Liang, Yong*; Zhu, Yi*; Zheng, Youxuan; Pan, Yi; Integrated redox-active reagents for photoinduced regio- and stereoselective fluorocarboborylation, Nat. Commun, 2020, 11(1): 2572. (6) Mao, Yu; Zhao, Wenxuan; Lu, Shuo; Yu, Lei; Wang, Yi*; Liang, Yong*; Ni, Shengyang*; Pan, Yi; Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study, Chem. Sci., 2020, 11(19): 4939-4947. (7) Zhang, Weigang; Huang, Mengjun; Zou, Zhenlei; Wu, Zhengguang; Ni, Shengyang; Kong, Lingyu; Zheng, Youxuan; Wang, Yi*; Pan, Yi; Redox-active benzimidazolium sulfonamides as cationic thiolating reagents for reductive cross-coupling of organic halides, Chem. Sci., 2021, 12: 2509-2514. (8) “Uranyl-catalysed C–H alkynylation and olefination”, Y. Mao, Y. Liu, L. Yu, S. Ni, Y. Wang* and Y. Pan. Org. Chem. Front., 2021, 8, 5968-5974. (9) “Electrochemical C–N bond activation for deaminative reductive coupling of Katritzky salts”, Yeqing Liu, X. Tao, Y. Mao, X.Yuan, J. Qiu, L. Kong, S. Ni*, K. Guo*, Y. Wang* and Y. Pan. Nat. Commun.2021, 12, 6745-6752. (10) “Electrochemical-Promoted Nickel-Catalyzed Oxidative Fluoroalkylation of Aryl Iodides”, Z. Zou , H. Li, M. Huang, W. Zhang*, S. Zhi, Y. Wang*, and Y. Pan. Org. Lett. 2021, 23, 21, 8252–8256. (11) “Branched-Selective Hydroacylation of Alkenes via Photoredox Cobalt and N-Heterocyclic Carbene Cooperative Triple Catalysis”,X. Tao, Q. Wang, L. Kong, S. Ni, Y. Pan, and Y. Wang*, ACS Catal. 2022, 12, 24, 15241–15248. (12) “Fast Prediction of Lipophilicity of Organofluorine Molecules: Deep Learning Derived Polarity Characters and Experimental Tests”, Q. Jia, Y. Ni, Z. Liu, X. Gu, Z. Cui, M. Fan, Q. Zhu*, Y. Wang*, Jing Ma*, J. Chem. Inf. Model.2022, 62, 4928−4936. (13) “Chiral-at-Cage Carboranes for Circularly Polarized Luminescenceand Aggregation-Induced Electrochemiluminescence”, J. Tong, Y.Cao, Y. Zhang, P. Wang, P. Wang, X. Liao, W. Zhang, Y. Wang*, Y. Zheng,* J. Zhu and Y. Pan., Angew. Chem.Int. Ed. 2022, e202209438. (14) “A photoinduced transient activating strategy for late-stage chemoselective C(sp3)–H trifluoromethylation of azines”,M. Huang, J.Ma, Z. Zou, H., Jiyang Liu, L. Kong, Y, Pan, W. Zhang,* Y. Liang* and Y. Wang*, Chem. Sci., 2022,13, 11312-11319. (15) “Photoexcited Direct Amination/Amidation of Inert Csp3–H Bonds via Tungsten–Nickel Catalytic Relay”,Q. Wang, S. Ni, L. Yu, Y. Pan, and Y. Wang*, ACS Catal. 2022, 12, 18, 11071–11077. (16) “A practical fluorosulfonylating platform via photocatalytic imidazolium-based SO2F radical reagent”, W. Zhang, H. Li, X. Li, Z. Zou, M. Huang, J. Liu, X. Wang, S. Ni, Y. Pan and Y. Wang*, Nat. Commun.2022, 13, 3515. (17) “Electrochemical-Promoted Nickel-Catalyzed Reductive Allylation of Aryl Halides”, W. Chen , S. Ni*, Yi Wang*, and Y. Pan. Org. Lett. 2022, 24, 20, 3647–3651. (18) “Radical boron migration of allylboronic esters”, X. Tao, S. Ni, L. Kong, Y. Wang* and Y. Pan. Chem. Sci., 2022, 13, 1946-1950. (19) “Visible-light-mediated tungsten catalyzed C−H amination of unactivated alkanes with nitroarenes”, Q. Wang , S. Ni , X. Wang , Y. Wang* and Y. Pan. Sci. China Chem, 2022, 65, 678-685. 课程名称、上课时间地点
有机化学(英文)周四9-10节 有机合成 周三5-6节 文献综述 周三3-4节 教学大纲、考试要求
教学资源(上课讲义、参考资料等)
课题组风采
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